Introductory Statistical Thermodynamics is a textual content for an introductory one-semester path in statistical thermodynamics for upper-level undergraduate and graduate scholars in physics and engineering. The booklet bargains a excessive point of element in derivations of all equations and effects. this data is critical for college kids to understand tricky options in physics which are had to stream directly to larger point classes. The textual content is basic, self contained, and mathematically well-founded, containing a few issues of precise recommendations to aid scholars to understand the tougher theoretical thoughts. starting chapters position an emphasis on quantum mechanicsIncludes issues of particular options and a few distinct theoretical derivations on the finish of every chapterProvides a excessive point of aspect in derivations of all equations and effects

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Extra resources for Introductory Statistical Thermodynamics

Example text

132), the operator R(α) is known as the shift operator. Its effect is to “shift” by α the argument of any function f (φ). 132) to our particular function (φ) = √1 exp(imφ). 132) and 2π simple algebra, we obtain ˆ R(α) (φ) = 1 (φ + α) = √ exp(im(φ + α)) 2π 1 = exp(imα) √ exp (i m φ) = R(α, m) (φ). 124), telling us that the the function ˆ eigenfunction of the shift operator R(α), with the eigenvalue equal to R(α, m) = exp(imα). 1 Introduction and Definitions Equilibrium macrostate of a thermodynamic system is usually specified by a few easily measurable macroscopic quantities.

2l)! 5 2 . 45), for arbitrary values of the integer m as follows: Plm (µ) = 1 1 − µ2 2l l! |m|/2 l dl+|m| µ2 − 1 . 98), we see that Plm (µ) and consequently the wave function ψlm (θ, φ) vanishes when |m| > l. Thus, we must have −l ≤ m ≤ +l. , different values of the angular momentum vector component in z-direction Lz . 98). 98). In order to calculate the normalization constants Alm , we need to calculate the integral +1 Ilm = dµ[Plm (µ)]2 . , Plm (µ) = 1 − µ2 m/2 dm Pl (µ) . 101) 1 − µ2 1/2 dPlm = Plm+1 − mµ 1 − µ2 dµ −1/2 Plm .

4) Lz = xpy − ypx . 1 Diatomic molecule as a rigid rotator. ϕ CM Introductory Statistical Thermodynamics. 00005-7 Copyright c 2011 Elsevier, Inc. All rights reserved. 4), we use the components of the linear momentum vector p = mv = (px , py , pz ) in Descartes co-ordinates. 3) is replaced by the Hamiltonian operator H ˆR = H 1 2 Lˆ 2 = Lˆ + Lˆ y2 + Lˆ z2 . 6) where (θ, φ) are the two spherical angular co-ordinates, which are suitable for the description of the rotational motion of the constituent particles.